Practical Organic Chemistry and PurificationmediumMCQ SINGLE⭐ Must-Do

In the qualitative test for sulphur, the addition of sodium nitroprusside to the Lassaigne's extractPractical Organic Chemistry and Purification Chemistry Question

Question

In the qualitative test for sulphur, the addition of sodium nitroprusside to the Lassaigne's extract yields a deep violet color due to the formation of:

Answer: A

💡 Solution & Explanation

The sulphide ion reacts with sodium nitroprusside to form the highly colored complex sodium thionitroprusside, $Na_4[Fe(CN)_5NOS]$.

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