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Why does Carbon dioxide () exist as a discrete gas molecule while Silicon dioxide () forms a giant 3p Block Elements Chemistry Question

Question

Why does Carbon dioxide ($CO_2$) exist as a discrete gas molecule while Silicon dioxide ($SiO_2$) forms a giant 3D solid network?

Answer: B

💡 Solution & Explanation

Carbon, being a small period 2 element, easily forms strong $p\pi-p\pi$ double bonds with oxygen to form linear $O=C=O$ molecules. Silicon is too large for effective $p\pi-p\pi$ overlap, so it forms strong single bonds with four oxygens, creating a giant 3D network.

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