The electron affinity (negative electron gain enthalpy) of Group 17 elements shows a notable anomaly — p Block Elements Chemistry Question
Question
The electron affinity (negative electron gain enthalpy) of Group 17 elements shows a notable anomaly. Which sequence correctly represents the decreasing order of electron affinity?
Answer: B
💡 Solution & Explanation
Chlorine has a higher electron affinity than Fluorine. The 2p orbitals of Fluorine are very compact, so adding an incoming electron causes strong inter-electronic repulsions, making it less favorable than adding it to the larger 3p orbitals of Chlorine.
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