Diborane () undergoes asymmetrical cleavage when treated with small, unhindered bases. What are the specific ionic products formed when diborane reacts with ammonia () at low temperatures?

Question

Diborane ($B_2H_6$) undergoes asymmetrical cleavage when treated with small, unhindered bases. What are the specific ionic products formed when diborane reacts with ammonia ($NH_3$) at low temperatures?

Prashant Kotian · Accepted Answer

Correct answer: C. Small amines like cause asymmetrical cleavage of the diborane dimer, yielding the ionic salt . In contrast, bulky amines cause symmetrical cleavage yielding neutral adducts.

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