Which of the following complex coordination compounds represents the highly water-soluble intermedia — Metallurgy and Isolation of Elements Chemistry Question
Question
Which of the following complex coordination compounds represents the highly water-soluble intermediate formed during the Baeyer's process digestion of Bauxite with concentrated aqueous $NaOH$?
Answer: C
💡 Solution & Explanation
In Baeyer's process, the amphoteric Aluminium oxide in Bauxite reacts with concentrated $NaOH$ at high pressure to form a soluble coordination complex: $Al_2O_3 \cdot 2H_2O + 2NaOH + H_2O \rightarrow 2Na[Al(OH)_4]_{(aq)}$. This complex is also frequently written in its simplified dehydrated form as Sodium meta-aluminate, $NaAlO_2$.
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