In the Hall's process for purifying low-grade red bauxite, the initial digestion step differs signif — Metallurgy and Isolation of Elements Chemistry Question
Question
In the Hall's process for purifying low-grade red bauxite, the initial digestion step differs significantly from Baeyer's process. What specific chemical reagent and condition is employed in Hall's process to solubilize the alumina?
Answer: B
💡 Solution & Explanation
Hall's process uses solid Sodium Carbonate ($Na_2CO_3$). The bauxite ore is fused with $Na_2CO_3$ to form water-soluble sodium aluminate ($NaAlO_2$): $Al_2O_3 + Na_2CO_3 \xrightarrow{Fuse} 2NaAlO_2 + CO_2 \uparrow$. Baeyer's process uses aqueous $NaOH$ under pressure, and Serpeck's uses Coke/$N_2$.
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