A major economic and operational drawback of the Hall-Heroult process is the continuous consumption — Metallurgy and Isolation of Elements Chemistry Question
Question
A major economic and operational drawback of the Hall-Heroult process is the continuous consumption of the graphite anodes, requiring their frequent replacement. Which anodic reaction dictates this consumption?
Answer: D
💡 Solution & Explanation
During the electrolysis, oxygen ions ($O^{2-}$) migrate to the anode and are discharged as oxygen gas. At the high operating temperatures ($\sim 900^\circ C$), this liberated oxygen aggressively attacks the solid carbon (graphite) anodes, burning them away as $CO$ and $CO_2$ gases.
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