Metallurgy and Isolation of ElementshardMCQ SINGLE⭐ Must-Do

Why are highly electropositive s-block elements (like Na, K, Mg, Ca) and Aluminium extracted exclusiMetallurgy and Isolation of Elements Chemistry Question

Question

Why are highly electropositive s-block elements (like Na, K, Mg, Ca) and Aluminium extracted exclusively via the electrolysis of their fused (molten) salts rather than their aqueous solutions?

Answer: B

💡 Solution & Explanation

Highly reactive metals sit above Hydrogen in the electrochemical series. If an aqueous solution is electrolyzed, the water molecules (or $H^+$ ions) are preferentially reduced at the cathode to form Hydrogen gas, leaving the metal ions in solution. Hence, anhydrous fused melts must be used.

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