A specific depressant, , is introduced into a flotation tank containing a mixture of Galena () and S — Metallurgy and Isolation of Elements Chemistry Question
Question
A specific depressant, $NaCN$, is introduced into a flotation tank containing a mixture of Galena ($PbS$) and Sphalerite ($ZnS$). What is the exact chemical reason this depressant facilitates their separation?
Answer: B
💡 Solution & Explanation
$NaCN$ acts as a selective depressant for $ZnS$. It reacts with $ZnS$ to form the stable, water-soluble coordination complex sodium tetracyanozincate(II), $Na_2[Zn(CN)_4]$. Because it dissolves, it cannot float, allowing $PbS$ to be skimmed off in the froth.
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