Isomerism and StereochemistryhardMCQ SINGLE⭐ Must-Do

In the advanced study of Conformational Isomerism of n-butane, what is the highly specific dihedral Isomerism and Stereochemistry Chemistry Question

Question

In the advanced study of Conformational Isomerism of n-butane, what is the highly specific dihedral (torsional) angle separating the two terminal methyl groups in the stable "Gauche" conformation?

Answer: C

💡 Solution & Explanation

Rotating around the central C2-C3 bond of n-butane generates several conformers. The Anti form (most stable) places the bulky methyls at $180^\circ$. The Gauche form staggers the methyls adjacent to each other to minimize immediate eclipse while not reaching full opposition. The exact dihedral angle defining this Gauche conformation is strictly $60^\circ$.

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