Isomerism and StereochemistryhardMCQ SINGLE⭐ Must-Do

Emil Fischer arbitrarily established the D/L Relative Configuration system. Which specific molecule Isomerism and Stereochemistry Chemistry Question

Question

Emil Fischer arbitrarily established the D/L Relative Configuration system. Which specific molecule was chosen as the universal standard reference, and how is the 'D' configuration defined?

Answer: C

💡 Solution & Explanation

The D/L relative configuration system is deeply anchored to the arbitrary historical standard of (+)-Glyceraldehyde (2,3-dihydroxypropanal). In its standard vertical Fischer projection, if the defining hydroxyl ($-OH$) group on the chiral center is oriented on the right side, the molecule is assigned the 'D' configuration. If on the left, it is 'L'.

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