When thermodynamically comparing the macroscopic physical properties of standard Cis and Trans geome — Isomerism and Stereochemistry Chemistry Question

💡 Solution & Explanation

Melting point heavily depends on solid-state packing efficiency. Trans isomers feature substituents symmetrically opposed across the double bond, granting them a highly linear and symmetrical profile. This allows them to pack extremely efficiently into a robust crystalline lattice, resulting in strong intermolecular crystal forces and a higher melting point than the bulky, poorly packing cis isomers.