Which of the following chemical systems serves as a classic example of a "Diad" tautomeric system? β Isomerism and Stereochemistry Chemistry Question
Question
Which of the following chemical systems serves as a classic example of a "Diad" tautomeric system?
Answer: B
π‘ Solution & Explanation
Tautomerism involves the rapid oscillation of a mobile atom between polyvalent atoms. In a Diad system, the hydrogen atom migrates strictly between two adjacent atoms (a 1,2-shift). The interconversion of Hydrogen Cyanide ($H-C\equiv N$) and Hydrogen Isocyanide ($H-N\equiv C$) perfectly illustrates a diad system, as the proton shifts directly from carbon to the adjacent nitrogen.
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