Ionic EquilibriummediumMCQ SINGLE⭐ Must-Do

If for at 25°C is 4.7, what is the pH of a 0.5 M aqueous solution?Ionic Equilibrium Chemistry Question

Question

If $p_b$ for $CN^-$ at 25°C is 4.7, what is the pH of a 0.5 M aqueous $NaCN$ solution?

Answer: A

💡 Solution & Explanation

$NaCN$ is a salt of WA-SB. $pK_b(CN^-) = 4.7 \implies pK_a(HCN) = 14 - 4.7 = 9.3$. Formula: $pH = 7 + \frac{1}{2}pK_a + \frac{1}{2}\log C = 7 + 4.65 + 0.5\log(0.5) = 11.65 - 0.15 = 11.5$.

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