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Which of the following alkyl halides is NOT suitable for preparing alkanes via Corey-House synthesisHydrocarbons Chemistry Question

Question

Which of the following alkyl halides is NOT suitable for preparing alkanes via Corey-House synthesis?

Answer: D

💡 Solution & Explanation

In the Corey-House synthesis, the alkyl halide reacting with the Gilman reagent ($R_2CuLi$) must be methyl or primary ($1^\circ$). A tertiary halide like tert-butyl bromide undergoes E2 elimination instead.

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