Which of the following alkyl halides is NOT suitable for preparing alkanes via Corey-House synthesis β Hydrocarbons Chemistry Question
Question
Which of the following alkyl halides is NOT suitable for preparing alkanes via Corey-House synthesis?
Answer: D
π‘ Solution & Explanation
In the Corey-House synthesis, the alkyl halide reacting with the Gilman reagent ($R_2CuLi$) must be methyl or primary ($1^\circ$). A tertiary halide like tert-butyl bromide undergoes E2 elimination instead.
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