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In the free radical chlorination of an alkane, which elementary step constitutes the rate-determininHydrocarbons Chemistry Question

Question

In the free radical chlorination of an alkane, which elementary step constitutes the rate-determining step?

Answer: A

💡 Solution & Explanation

The hydrogen abstraction step ($R-H + Cl^\bullet \rightarrow R^\bullet + HCl$) requires the highest activation energy in the propagation phase and forms the intermediate radical, determining the reaction rate and selectivity.

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