Which of the following alkyl halides is NOT suitable for preparing alkanes via the Corey-House synth — Hydrocarbons Chemistry Question
Question
Which of the following alkyl halides is NOT suitable for preparing alkanes via the Corey-House synthesis with a Gilman reagent?
Answer: A
💡 Solution & Explanation
In Corey-House synthesis, the alkyl halide ($R'-X$) must be primary or methyl. A tertiary halide like $(CH_3)_3CBr$ undergoes E2 elimination due to the basicity of the cuprate.
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