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If sodium benzoate labeled with a radioactive Carbon-14 atom exclusively at the carboxylate carbon (Hydrocarbons Chemistry Question

Question

If sodium benzoate labeled with a radioactive Carbon-14 atom exclusively at the carboxylate carbon ($C_6H_5-^{14}COONa$) is heated with soda-lime, where is the radioactivity found?

Answer: A

💡 Solution & Explanation

Decarboxylation completely removes the carboxylate group ($-COONa$) from the ring. It combines with the basic $NaOH$ to form sodium carbonate. Thus, the heavy isotope never enters the benzene ring.

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