An unknown hydrocarbon reacts with ammoniacal cuprous chloride () to form a red precipitate. Which o β Hydrocarbons Chemistry Question
Question
An unknown hydrocarbon reacts with ammoniacal cuprous chloride ($Cu_2Cl_2/NH_4OH$) to form a red precipitate. Which of the following structures is consistent with this observation?
Answer: A
π‘ Solution & Explanation
This reagent tests for terminal alkynes. The highly electronegative sp-hybridized carbon renders the terminal hydrogen slightly acidic, allowing it to be replaced by copper to form a red copper acetylide precipitate. 1-butyne is terminal.
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