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Which of the following isotopic methyl groups exerts the STRONGEST (electron-donating) inductive effGOC and Organic Chemistry Basics Chemistry Question

Question

Which of the following isotopic methyl groups exerts the STRONGEST $+I$ (electron-donating) inductive effect when attached to a carbon chain?

Answer: C

💡 Solution & Explanation

Heavier isotopes of hydrogen form shorter, stronger bonds with carbon that vibrate less. This localizes the electron density closer to the carbon nucleus, resulting in a stronger $+I$ push into the main chain. The order is $-CT_3 > -CD_3 > -CH_3$.

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