Arrange the following compounds in decreasing order of their acidic strength: (I) Phenol, (II) p-Cre — GOC and Organic Chemistry Basics Chemistry Question
Question
Arrange the following compounds in decreasing order of their acidic strength: (I) Phenol, (II) p-Cresol, (III) m-Nitrophenol, (IV) p-Nitrophenol.
Answer: A
💡 Solution & Explanation
p-Cresol (II) has a destabilizing $+H, +I$ group (weakest). Phenol (I) is the reference. m-Nitrophenol (III) has a $-I$ effect. p-Nitrophenol (IV) is stabilized by powerful $-M$ and $-I$ effects. Order: IV > III > I > II.
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