Halogens () exhibit a unique interplay of electronic effects when attached to an aromatic ring. Whic — GOC and Organic Chemistry Basics Chemistry Question
Question
Halogens ($-F, -Cl, -Br, -I$) exhibit a unique interplay of electronic effects when attached to an aromatic ring. Which statement correctly describes their net influence?
Answer: B
💡 Solution & Explanation
Halogens are the primary exception to the "+M > -I" rule. Because they are highly electronegative, their electron-withdrawing $-I$ effect dominates overall reactivity (deactivating the ring). However, their lone pairs still dictate that incoming electrophiles attack the ortho/para positions via $+M$ resonance.
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