d and f Block ElementsmediumMCQ SINGLE⭐ Must-Do

Due to the Lanthanide Contraction, the basic character of the lanthanoid trihydroxides () exhibits ad and f Block Elements Chemistry Question

Question

Due to the Lanthanide Contraction, the basic character of the lanthanoid trihydroxides ($Ln(OH)_3$) exhibits a distinct trend. Which of the following defines this trend accurately?

Answer: A

💡 Solution & Explanation

The ionic radius of $Ln^{3+}$ cations strictly decreases from $La$ to $Lu$. As the cation shrinks, its polarizing power increases, increasing the covalent character of the $Ln-OH$ bond, thereby decreasing its basicity in water.

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