Due to the Lanthanide Contraction, the basic character of the lanthanoid trihydroxides () exhibits a — d and f Block Elements Chemistry Question
Question
Due to the Lanthanide Contraction, the basic character of the lanthanoid trihydroxides ($Ln(OH)_3$) exhibits a distinct trend. Which of the following defines this trend accurately?
Answer: A
💡 Solution & Explanation
The ionic radius of $Ln^{3+}$ cations strictly decreases from $La$ to $Lu$. As the cation shrinks, its polarizing power increases, increasing the covalent character of the $Ln-OH$ bond, thereby decreasing its basicity in water.
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