The ion is thermodynamically unstable in an aqueous medium and undergoes rapid disproportionation in β d and f Block Elements Chemistry Question
Question
The $Cu^+$ ion is thermodynamically unstable in an aqueous medium and undergoes rapid disproportionation into $Cu^{2+}$ and $Cu^0$. What is the driving force for this specific reaction?
Answer: B
π‘ Solution & Explanation
While $Cu^+$ has a stable $d^{10}$ configuration, the $Cu^{2+}$ ion ($d^9$) has a much higher charge density. When placed in water, the massive release of hydration energy by $Cu^{2+}$ completely overcompensates for the second ionization energy, driving the disproportionation.
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