The oxidation state is the universally dominant and most stable state for all lanthanoids. However, — d and f Block Elements Chemistry Question
Question
The $+3$ oxidation state is the universally dominant and most stable state for all lanthanoids. However, Cerium ($Z=58$) readily forms a stable $+4$ ion. In aqueous chemical reactions, how does $Ce^{4+}$ characteristically behave?
Answer: D
💡 Solution & Explanation
Although $Ce^{4+}$ achieves stability by possessing an empty $4f^0$ core, the overarching thermodynamic hydration stability of the entire series strictly favors $+3$. Therefore, $Ce^{4+}$ has an immense drive to capture an electron and become $Ce^{3+}$, acting as an aggressive oxidizing agent.
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