d and f Block ElementshardMCQ SINGLE⭐ Must-Do

The intense, vibrant purple colour of the aqueous permanganate ion () is a heavily tested visual phed and f Block Elements Chemistry Question

Question

The intense, vibrant purple colour of the aqueous permanganate ion ($MnO_4^-$) is a heavily tested visual phenomenon. Because the central Manganese is in a strictly $d^0$ oxidation state, this colour CANNOT be attributed to $d-d$ transitions. What causes it?

Answer: D

💡 Solution & Explanation

A $d-d$ transition requires at least one $d$ -electron. Since $Mn^{7+}$ is $d^0$, the intense purple colour arises entirely from Charge Transfer. Visible light excites an electron from the ligand (Oxygen) momentarily into the empty metal $d$ -orbital.

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