The intense, vibrant purple colour of the aqueous permanganate ion () is a heavily tested visual phe — d and f Block Elements Chemistry Question
Question
The intense, vibrant purple colour of the aqueous permanganate ion ($MnO_4^-$) is a heavily tested visual phenomenon. Because the central Manganese is in a strictly $d^0$ oxidation state, this colour CANNOT be attributed to $d-d$ transitions. What causes it?
Answer: D
💡 Solution & Explanation
A $d-d$ transition requires at least one $d$ -electron. Since $Mn^{7+}$ is $d^0$, the intense purple colour arises entirely from Charge Transfer. Visible light excites an electron from the ligand (Oxygen) momentarily into the empty metal $d$ -orbital.
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