During a volumetric titration utilizing Potassium Permanganate in a neutral or faintly alkaline medi — d and f Block Elements Chemistry Question
Question
During a volumetric titration utilizing Potassium Permanganate in a neutral or faintly alkaline medium, what is the exact equivalent weight of the $KMnO_4$ utilized? (Let M represent the molar mass of $KMnO_4$).
Answer: B
💡 Solution & Explanation
The basic "BAN" rule for $KMnO_4$ n-factors: Basic (strongly alkaline to manganate) = 1, Acidic = 5, Neutral/faintly alkaline = 3. In neutral media, $Mn^{7+}$ reduces to a black precipitate of $MnO_2$ ($Mn^{4+}$), a 3-electron change. Thus, Eq. Wt = $M/3$.
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