In Crystal Field Theory, when six ligands approach a central metal ion to form an octahedral complex β Coordination Compounds Chemistry Question
Question
In Crystal Field Theory, when six ligands approach a central metal ion to form an octahedral complex, which d-orbitals experience the maximum electrostatic repulsion and form the higher energy $e_g$ set?
Answer: B
π‘ Solution & Explanation
In an octahedral field, ligands approach directly along the Cartesian axes (x, y, z). The axial orbitals ($d_{x^2-y^2}$ and $d_{z^2}$) point directly at the approaching ligands and experience maximum repulsion, becoming the raised $e_g$ set.
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