Coordination CompoundsmediumMCQ SINGLE⭐ Must-Do

According to Valence Bond Theory (VBT), what is the hybridisation and geometry of the diamagnetic coCoordination Compounds Chemistry Question

Question

According to Valence Bond Theory (VBT), what is the hybridisation and geometry of the diamagnetic complex $[Ni(CN)_4]^{2-}$?

Answer: B

💡 Solution & Explanation

$Ni^{2+}$ has a $3d^8$ configuration. $CN^-$ is a strong field ligand, forcing pairing of the two unpaired 3d electrons. This vacates one 3d orbital, resulting in $dsp^2$ hybridisation and a square planar geometry.

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