Coordination CompoundsmediumMCQ SINGLE⭐ Must-Do

The complex exhibits paramagnetism with 3 unpaired electrons. What is its hybridisation state accordCoordination Compounds Chemistry Question

Question

The complex $[Cr(H_2O)_6]^{3+}$ exhibits paramagnetism with 3 unpaired electrons. What is its hybridisation state according to VBT?

Answer: B

💡 Solution & Explanation

$Cr^{3+}$ has a $3d^3$ configuration. According to Hund's rule, the 3 electrons occupy three 3d orbitals singly, leaving two inner 3d orbitals completely empty. Thus, it seamlessly undergoes inner orbital $d^2sp^3$ hybridisation regardless of ligand strength.

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