Coordination CompoundsmediumMCQ SINGLE⭐ Must-Do

What is the IUPAC name for Sodium nitroprusside, ?Coordination Compounds Chemistry Question

Question

What is the IUPAC name for Sodium nitroprusside, $Na_2[Fe(CN)_5NO]$?

Answer: B

💡 Solution & Explanation

The NO ligand acts as $NO^+$ (nitrosonium/nitrosyl). Charge balance: $2(+1) + x + 5(-1) + (+1) = 0 \Rightarrow x = +2$. As the sphere is anionic, it is ferrate(II). Name: Sodium pentacyanidonitrosylferrate(II).

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