Chemical KineticshardMCQ SINGLE⭐ Must-Do

The Van't Hoff differential method utilizes the initial instantaneous rates ( and ) at two differentChemical Kinetics Chemistry Question

Question

The Van't Hoff differential method utilizes the initial instantaneous rates ($r_1$ and $r_2$) at two different initial concentrations ($c_1$ and $c_2$) to deduce kinetic order. The correct mathematical expression for the reaction order $n$ is:

Answer: A

💡 Solution & Explanation

Applying logarithms to the rate law $r = k c^n$ yields $\log r = \log k + n \log c$. Setting this up for two separate states and subtracting them perfectly eliminates the constant $\log k$, resulting in $\log r_1 - \log r_2 = n(\log c_1 - \log c_2)$. This isolates to $n = \frac{\log(r_1/r_2)}{\log(c_1/c_2)}$.

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