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Despite Fluorine being more electronegative than Hydrogen, the dipole moment of () is significantly Chemical Bonding Chemistry Question

Question

Despite Fluorine being more electronegative than Hydrogen, the dipole moment of $NH_3$ ($1.47\text{ D}$) is significantly higher than that of $NF_3$ ($0.23\text{ D}$). This anomaly occurs because:

Answer: B

💡 Solution & Explanation

Both are pyramidal. In $NH_3$, bond dipoles point toward N, reinforcing the lone pair's upward vector. In $NF_3$, bond dipoles point toward the highly electronegative F atoms (away from N), mostly cancelling the upward lone pair vector.

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