Identify the exact nature of the multi-center bonding architecture present in diborane (). β Chemical Bonding Chemistry Question
Question
Identify the exact nature of the multi-center bonding architecture present in diborane ($B_2H_6$).
Answer: B
π‘ Solution & Explanation
Diborane is an electron-deficient hydride. The 4 terminal $B-H$ bonds are normal covalent 2-center-2-electron ($2c-2e$) bonds. The two central bridging hydrogens form 3-center-2-electron ($3c-2e$) "banana" bonds, sharing 2 electrons across 3 nuclei ($B-H-B$).
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