Which of the following diatomic species contains solely bonds with exactly zero bonds according to M — Chemical Bonding Chemistry Question
Question
Which of the following diatomic species contains solely $\pi$ bonds with exactly zero $\sigma$ bonds according to MOT?
Answer: C
💡 Solution & Explanation
$C_2$ has 12 electrons. Its valence MOT configuration is $\sigma 2s^2, \sigma^* 2s^2, \pi 2p_x^2 = \pi 2p_y^2$. The last 4 bonding electrons exclusively occupy the $\pi$ bonding orbitals, resulting in a bond order of 2 that consists of two $\pi$ bonds and no $\sigma$ bonds.
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