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Fructose is a ketohexose. Despite lacking a free aldehyde group, it readily reduces Fehling's solutiBiomolecules Chemistry Question

Question

Fructose is a ketohexose. Despite lacking a free aldehyde group, it readily reduces Fehling's solution and Tollen's reagent. This chemical behavior is primarily due to:

Answer: B

💡 Solution & Explanation

In alkaline mediums like Fehling's and Tollen's reagents, fructose isomerizes (Lobry de Bruyn-van Ekenstein rearrangement) via an enediol intermediate into reducing aldoses like glucose and mannose.

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