When sucrose is hydrolyzed in the presence of an acid, the resulting aqueous solution gradually chan — Biomolecules Chemistry Question
Question
When sucrose is hydrolyzed in the presence of an acid, the resulting aqueous solution gradually changes its overall optical rotation from dextrorotatory ($+66.5^\circ$) to laevorotatory. What is the fundamental cause of this specific "inversion"?
Answer: C
💡 Solution & Explanation
Acidic hydrolysis of sucrose (invert sugar) breaks it into equimolar D-glucose and D-fructose. The net rotation of the mixture becomes negative because the laevorotation of fructose ($-92.4^\circ$) exceeds the dextrorotation of glucose ($+52.5^\circ$).
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