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When sucrose is hydrolyzed in the presence of an acid, the resulting aqueous solution gradually chanBiomolecules Chemistry Question

Question

When sucrose is hydrolyzed in the presence of an acid, the resulting aqueous solution gradually changes its overall optical rotation from dextrorotatory ($+66.5^\circ$) to laevorotatory. What is the fundamental cause of this specific "inversion"?

Answer: C

💡 Solution & Explanation

Acidic hydrolysis of sucrose (invert sugar) breaks it into equimolar D-glucose and D-fructose. The net rotation of the mixture becomes negative because the laevorotation of fructose ($-92.4^\circ$) exceeds the dextrorotation of glucose ($+52.5^\circ$).

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