Why is the trifluoromethyl group () a powerful meta-director in electrophilic aromatic substitution? — Aromatic Hydrocarbons Chemistry Question
Question
Why is the trifluoromethyl group ($-CF_3$) a powerful meta-director in electrophilic aromatic substitution?
Answer: B
💡 Solution & Explanation
The $-CF_3$ group is powerfully electron-withdrawing. If attack occurs at ortho/para positions, one resonance structure places two positive charges directly adjacent to each other. Meta attack avoids this catastrophically unstable structure.
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