Cyclooctatetraene (COT) possesses electrons. How does this molecule avoid the massive destabilizatio β Aromatic Hydrocarbons Chemistry Question
Question
Cyclooctatetraene (COT) possesses $8\pi$ electrons. How does this molecule avoid the massive destabilization associated with anti-aromaticity?
Answer: D
π‘ Solution & Explanation
With $8\pi$ electrons, a planar COT would be anti-aromatic. To escape this destabilization, the molecule adopts a non-planar tub conformation, destroying continuous $p$ -orbital overlap and becoming a non-aromatic polyene.
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