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During a Friedel-Crafts acylation, why is it necessary to use more than one full stoichiometric equiAromatic Hydrocarbons Chemistry Question

Question

During a Friedel-Crafts acylation, why is it necessary to use more than one full stoichiometric equivalent of the Lewis acid catalyst ($AlCl_3$)?

Answer: C

💡 Solution & Explanation

Unlike alkylation, the ketone product of acylation acts as a Lewis base and forms a highly stable complex with $AlCl_3$, completely removing it from the catalytic cycle. Thus, excess catalyst is required.

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