What is the active electrophile generated when fuming sulfuric acid (oleum) is used in the sulfonati — Aromatic Hydrocarbons Chemistry Question
Question
What is the active electrophile generated when fuming sulfuric acid (oleum) is used in the sulfonation of benzene?
Answer: C
💡 Solution & Explanation
In sulfonation, the active electrophile is sulfur trioxide ($SO_3$), which is highly electron-deficient due to its three strongly polarized $S=O$ bonds, even though it carries no formal positive charge.
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