Why is the trifluoromethyl group (-) a powerful meta-director in electrophilic aromatic substitution — Aromatic Hydrocarbons Chemistry Question
Question
Why is the trifluoromethyl group (-$CF_3$) a powerful meta-director in electrophilic aromatic substitution?
Answer: C
💡 Solution & Explanation
The -CF3 group is powerfully electron-withdrawing. If attack occurs at ortho/para positions, one resonance structure places two positive charges directly adjacent to each other, which is highly unstable. Meta attack avoids this catastrophic structure.
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