Aromatic HydrocarbonshardMCQ SINGLE⭐ Must-Do

What is the major organic product formed when benzene is reacted with 1-chloro-2,2-dimethylpropane (Aromatic Hydrocarbons Chemistry Question

Question

What is the major organic product formed when benzene is reacted with 1-chloro-2,2-dimethylpropane (neopentyl chloride) in the presence of anhydrous $AlCl_3$?

Answer: C

💡 Solution & Explanation

Neopentyl chloride forms a primary complex which instantly undergoes a 1,2-methyl shift to form the highly stable tertiary carbocation (t-pentyl cation). Attack on benzene yields 2-methyl-2-phenylbutane.

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