For most EAS reactions like nitration and bromination, the primary kinetic isotope effect (kH/kD) is — Aromatic Hydrocarbons Chemistry Question
Question
For most EAS reactions like nitration and bromination, the primary kinetic isotope effect (kH/kD) is approximately 1. What does this observation conclusively prove?
Answer: C
💡 Solution & Explanation
Since replacing Hydrogen with Deuterium (which has a stronger bond) does not slow down the overall reaction rate, the C-H bond must be breaking in a fast step that does not bottleneck the reaction.
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