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Benzene diazonium chloride undergoes an electrophilic aromatic substitution coupling reaction with pAmines Chemistry Question

Question

Benzene diazonium chloride undergoes an electrophilic aromatic substitution coupling reaction with phenol to form an orange azo dye. What is the optimal pH environment for this reaction?

Answer: C

💡 Solution & Explanation

The diazonium cation is a weak electrophile. A mildly basic medium (pH 9-10) accurately converts the phenol into the vastly more nucleophilic phenoxide ion, immensely accelerating the coupling while avoiding the highly basic destruction of the diazonium salt.

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