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When a pure secondary () amine is thoroughly subjected to Hinsberg's test (reaction with benzenesulpAmines Chemistry Question

Question

When a pure secondary ($2^\circ$) amine is thoroughly subjected to Hinsberg's test (reaction with benzenesulphonyl chloride followed by excess $KOH$), what is observed?

Answer: B

💡 Solution & Explanation

A $2^\circ$ amine reacts to generate an N,N-dialkylbenzenesulphonamide. Because the nitrogen is fully alkylated, it totally lacks any remaining acidic $N-H$ protons. Consequently, it cannot react with the strong $KOH$ base and remains a water-insoluble solid.

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