During qualitative analysis, an unknown amine reacts with cold and to form a distinct, heavy yellow — Amines Chemistry Question
Question
During qualitative analysis, an unknown amine reacts with cold $NaNO_2$ and $HCl$ to form a distinct, heavy yellow oily liquid. What is the structural classification of this amine?
Answer: B
💡 Solution & Explanation
Both aliphatic and aromatic secondary ($2^\circ$) amines lack the hydrogen atoms to form diazonium species. They react cleanly with nitrous acid to form characteristic, water-insoluble N-nitrosamines, which physically present as distinct yellow oily liquids.
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