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In an aqueous solution, what is the correct decreasing order of basic strength specifically for ethyAmines Chemistry Question

Question

In an aqueous solution, what is the correct decreasing order of basic strength specifically for ethyl-substituted aliphatic amines?

Answer: A

💡 Solution & Explanation

For the larger ethyl group, the +I effect is much stronger, pushing the 3° amine ahead of the 1° amine despite poor hydration. However, the 2° amine maintains the optimal thermodynamic balance, resulting in the order $2^\circ > 3^\circ > 1^\circ > NH_3$.

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