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What is the correct decreasing order of boiling points for the isomeric amines: 1-Butanamine, DiethyAmines Chemistry Question

Question

What is the correct decreasing order of boiling points for the isomeric amines: 1-Butanamine, Diethylamine, and Ethyldimethylamine?

Answer: D

💡 Solution & Explanation

Boiling point heavily depends on intermolecular hydrogen bonding. 1-Butanamine ($1^\circ$) has two $N-H$ bonds for extensive H-bonding. Diethylamine ($2^\circ$) has one $N-H$ bond. Ethyldimethylamine ($3^\circ$) lacks $N-H$ bonds entirely. Therefore, $1^\circ > 2^\circ > 3^\circ$.

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